Determination of sulfonamides in swine meat by immunoaffinity chromatography

J AOAC Int. 2000 Jul-Aug;83(4):830-6.

Abstract

A procedure was developed for the preparation of anti-sulfonamide (SA) group-specific antibodies and immunosorbents. Sulfonamide haptens and conjugates were synthesized by building spacer arms on an N1 group of 4-aminobenzensulfonamide. The anti-SA group-specific antibodies and immunosorbents were prepared successfully. After extraction with methanol-water (8 + 2), sulfamonomethoxine, sulfadimethoxine, and sulfaquinoxaline were cleaned up on immunoaffinity columns and determined by reversed-phase liquid chromatography with UV detection at 270 nm. The recoveries from fortified swine meat (10-100 microg/kg) ranged from 70.8 to 94.1%, with coefficients of variation of 3.4-12.9%. Limits of detection were 1-2 microg/kg.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antibody Specificity
  • Antigens / chemistry
  • Antigens / immunology
  • Chromatography, Affinity / methods*
  • Haptens / chemistry
  • Haptens / immunology
  • Immunosorbent Techniques*
  • Meat / analysis*
  • Quality Control
  • Serum Albumin, Bovine
  • Sulfanilamide
  • Sulfanilamides / immunology
  • Sulfonamides / analysis*
  • Sulfonamides / immunology
  • Swine*

Substances

  • Antigens
  • Haptens
  • Sulfanilamides
  • Sulfonamides
  • Sulfanilamide
  • Serum Albumin, Bovine