Method for the analysis of thyreostats in meat tissue using gas chromatography with nitrogen phosphorus detection and tandem mass spectrometric confirmation

J Chromatogr Sci. 2001 May;39(5):195-9. doi: 10.1093/chromsci/39.5.195.

Abstract

An analytical method not requiring a mercury column cleanup step is described for the isolation and detection of four thyreostatic agents in meat tissue. The use of these growth promotants in livestock has been banned by regulatory agencies. The meat tissue is homogenized with acetonitrile-water, centrifuged, and the supernatant is partitioned with petroleum ether. The acetonitrile-water is concentrated and then passed through a silica-gel column. The solvent is then removed and the residue derivatized with N-methyl-N-(trimethylsilyl)-trifluoroacetamide. The total amount of organic solvent used for the analysis is merely 35 mL. The derivatized thyreostats are detected and quantitated by gas chromatography (GC) equipped with a nitrogen-phosphorus detector. Percent recoveries from fortified meat tissue (n = 6) at the 0.1-microg/g (parts per million) level are 93.5 +/- 2.9 for 2-thiouracil, 90.3 +/- 3.0 for tapazole, 87.5 +/- 2.9 for 6-methyl-2-thiouracil, and 85.1 +/- 5.8 for 6-n-propyl-2-thiouracil. For the confirmation of analyte identities, GC-tandem mass spectrometry with an ion-trap instrument is used. The estimated minimum level for a reliable measurement is 0.050 microg/g in meat tissue.

MeSH terms

  • Animals
  • Antithyroid Agents / analysis*
  • Cattle
  • Gas Chromatography-Mass Spectrometry / methods*
  • Meat Products / analysis*
  • Sensitivity and Specificity
  • Swine

Substances

  • Antithyroid Agents