Deuterium exchange during acid-demineralisation

Geochim Cosmochim Acta. 1988:52:2251-5. doi: 10.1016/0016-7037(88)90127-5.

Abstract

Isotopic analyses of residues prepared by demineralisation of the Murchison meteorite using D-labelled reagents provide evidence for measurable exchange of H-isotopes between residue and reagents. Precise quantification of this effect is precluded by substantial inhomogeneity of the meteoritic organic matter. A conservative estimate of the degree of exchange is 3 to 5% of the H pyrolysable as H2O. This could affect the shape of the curve defining D-release as a function of temperature, but does not change conclusions previously drawn concerning the nature of the bulk D-enrichment of insoluble organic matter in meteorites.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Astronomical Phenomena
  • Astronomy
  • Deuterium / chemistry*
  • Geological Phenomena
  • Geology
  • Hydrogen / chemistry*
  • Isotopes
  • Meteoroids*
  • Water / chemistry*

Substances

  • Isotopes
  • Water
  • Hydrogen
  • Deuterium