Amyloid formation in rat transthyretin: effect of oxidative stress

Clin Chim Acta. 2002 Sep;323(1-2):129-37. doi: 10.1016/s0009-8981(02)00179-1.

Abstract

Background: Transgenic mice carrying a human mutant transthyretin (TTR) gene are too small for in vivo experiments. It is necessary to have rat TTR protein and its antibody to overcome this problem.

Methods: Posttranslational modification of purified TTR was analyzed by means of matrix-assisted laser desorption ionization/time-of-flight mass spectrometry (MALDI/TOF-MS). Production of amyloid fibrils in vitro was confirmed by thioflavin T test and electron microscopy. Amyloidogenicity of rat TTR from rats with or without challenging paraquat was compared in vitro by thioflavin T test.

Results: MALDI/TOF-MS for rat TTR revealed three major modified forms-sulfate-conjugated, Cys-conjugated and glutathione-conjugated-in addition to the unconjugated (free) form of TTR. Although rat TTR in buffer of pH 7.0 could not make amyloid fibrils, rat TTR at pH 2.0-3.5 significantly formed amyloid fibrils, as confirmed by the thioflavin T test and electron microscopy. TTR purified from rats administered 4 mg/kg of paraquat formed much more amyloid fibrils than that from normal rats at pH 2.0-3.5 and significant amyloid fibrils were confirmed even at pH 7.0.

Conclusions: Rat TTR may be a valuable experimental tool for examination of the amyloidogenicity of senile systemic amyloidosis (SSA) as well as familial amyloidotic polyneuropathy (FAP) both in vitro and in vivo.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amyloid / chemistry*
  • Amyloid / ultrastructure
  • Animals
  • Benzothiazoles
  • Chromatography, Affinity
  • Chromatography, Gel
  • Electrophoresis, Polyacrylamide Gel
  • Hydrogen-Ion Concentration
  • Male
  • Microscopy, Electron
  • Oxidative Stress*
  • Paraquat
  • Prealbumin / chemistry*
  • Prealbumin / isolation & purification
  • Prealbumin / ultrastructure
  • Protein Processing, Post-Translational
  • Rats
  • Rats, Wistar
  • Sequence Analysis, Protein
  • Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
  • Thiazoles

Substances

  • Amyloid
  • Benzothiazoles
  • Prealbumin
  • Thiazoles
  • thioflavin T
  • Paraquat