Formation of disulfide bonds and homodimers of the major cat allergen Fel d 1 equivalent to the natural allergen by expression in Escherichia coli

J Biol Chem. 2003 Oct 10;278(41):40144-51. doi: 10.1074/jbc.M301416200. Epub 2003 May 5.

Abstract

Dander from the domestic cat (Felis domesticus) is one of the most common causes of IgE-mediated allergy. Attempts to produce tetrameric folded major allergen Fel d 1 by recombinant methods with structural features similar to the natural allergen have been only partially successful. In this study, a recombinant folded Fel d 1 with molecular and biological properties similar to the natural counterpart was produced. A synthetic gene coding for direct fusion of the Fel d 1 chain 2 N-terminally to chain 1 was constructed by overlapping oligonucleotides in PCR. Escherichia coli expression resulted in a non-covalently associated homodimer with an apparent molecular mass of 30 kDa defined by size exclusion chromatography. Furthermore, each 19,177-Da subunit displayed a disulfide pattern identical to that found in the natural Fel d 1, i.e. Cys3(1) Cys73(2), Cys44(1)-Cys48(2), Cys70(1)-Cys7(2), as determined by electrospray mass spectrometry after tryptic digestion. Circular dichroism analysis showed identical folds of natural and recombinant Fel d 1. Furthermore, recombinant Fel d l reacted specifically with serum IgE, inducing expression of CD203c on basophils and lymphoproliferative responses in cat-allergic patients. The results show that the overall fold and immunological properties of the recombinant Fel d 1 are very similar to those of natural Fel d 1. Moreover, the recombinant Fel d 1 construct provides a tool for defining the three-dimensional structure of Fel d 1 and represents a reagent for diagnosis and allergen-specific immunotherapy of cat allergy.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Allergens / chemistry*
  • Allergens / genetics
  • Amino Acid Sequence
  • Animals
  • Cats
  • Circular Dichroism
  • Dimerization
  • Disulfides / chemistry
  • Escherichia coli / genetics
  • Gene Expression
  • Glycoproteins / chemistry*
  • Glycoproteins / genetics
  • Glycoproteins / immunology
  • Humans
  • Hypersensitivity / immunology
  • Immunochemistry
  • Immunoglobulin E / blood
  • In Vitro Techniques
  • Lymphocyte Activation
  • Molecular Sequence Data
  • Protein Folding
  • Protein Structure, Quaternary
  • Protein Structure, Secondary
  • Recombinant Fusion Proteins / chemistry
  • Recombinant Fusion Proteins / genetics
  • Spectrometry, Mass, Electrospray Ionization

Substances

  • Allergens
  • Disulfides
  • Glycoproteins
  • Recombinant Fusion Proteins
  • Immunoglobulin E
  • Fel d 1 protein, Felis domesticus