Purification and characterization of a recombinant murine interleukin-6. Isolation of N- and C-terminally truncated forms

Eur J Biochem. 1992 Aug 1;207(3):903-13. doi: 10.1111/j.1432-1033.1992.tb17123.x.

Abstract

Murine interleukin-6 (IL-6), when expressed in Escherichia coli using the pUC9 vector, accumulated as insoluble aggregates or 'inclusion bodies'. After selective urea washing of the inclusion bodies, to remove extraneous proteins, murine IL-6 was solubilized with 8 M guanidine hydrochloride and then rapidly purified to homogeneity by gel-permeation chromatography followed by reversed-phase HPLC. It was demonstrated that complete disulfide bond formation in murine IL-6 occurred during the early urea washing/guanidine hydrochloride extraction steps, so no refolding step was required. When fully reduced murine IL-6 was dissolved in 8 M guanidine hydrochloride and allowed to air-oxidize, complete disulfide bond formation, monitored by analytical reversed-phase HPLC, was shown to occur within 13 h at 6 degrees C. About 25 mg pure protein was obtained from 37 g wet cells. This recombinant murine IL-6 had a specific activity in the hybridoma growth factor assay of 2 x 10(8) U/mg, which is equivalent to that of native murine IL-6. During the purification procedure, a number of variant forms of murine IL-6 were isolated and partially characterized. Two of these forms, T1 and T3, were C-terminal deletants of murine IL-6 lacking about 60 and 20 amino acids from the C-terminus, respectively, while the other form, T2, was an N-terminal deletant lacking 37 amino acids from the N-terminus. None of these variant forms of murine IL-6 bound to the murine IL-6 receptor and, consequently, all were inactive in the hybridoma growth factor assay.

MeSH terms

  • Amino Acids / analysis
  • Animals
  • Blotting, Western
  • Chromatography, Gel
  • Chromatography, High Pressure Liquid
  • Circular Dichroism
  • Disulfides / chemistry
  • Electrophoresis, Polyacrylamide Gel
  • Escherichia coli / genetics
  • Genetic Vectors
  • Interleukin-6 / chemistry
  • Interleukin-6 / isolation & purification*
  • Interleukin-6 / metabolism
  • Isoelectric Focusing
  • Kinetics
  • Mass Spectrometry
  • Mice
  • Protein Conformation
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / isolation & purification*
  • Recombinant Proteins / metabolism

Substances

  • Amino Acids
  • Disulfides
  • Interleukin-6
  • Recombinant Proteins