Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores

Nermeen W Aboelella; John T York; Anne M Reynolds; Koyu Fujita; Christopher R Kinsinger; Christopher J Cramer; Charles G Riordan; William B Tolman

doi:10.1039/b404640d

Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores

Chem Commun (Camb). 2004 Aug 7:(15):1716-7. doi: 10.1039/b404640d. Epub 2004 Jun 29.

Authors

Nermeen W Aboelella¹, John T York, Anne M Reynolds, Koyu Fujita, Christopher R Kinsinger, Christopher J Cramer, Charles G Riordan, William B Tolman

Affiliation

¹ Department of Chemistry, Center for Metals in Biocatalysis, Supercomputer Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.

PMID: 15278152
DOI: 10.1039/b404640d

Abstract

Two highly reactive heterodinuclear bis(mu-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at -80 degrees C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.

Publication types

Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, U.S. Gov't, P.H.S.

MeSH terms

Copper / chemistry*
Hydrogen Peroxide
Nickel / chemistry*
Organometallic Compounds / chemical synthesis
Organometallic Compounds / chemistry*
Oxidation-Reduction
Palladium / chemistry*

Substances

Organometallic Compounds
Palladium
Copper
Nickel
Hydrogen Peroxide

Grants and funding

GM 47365/GM/NIGMS NIH HHS/United States