The sulfogalactose moiety of sulfoglycosphingolipids serves as a mimic of tyrosine phosphate in many recognition processes. Prediction and demonstration of Src homology 2 domain/sulfogalactose binding

J Biol Chem. 2005 Apr 1;280(13):12542-7. doi: 10.1074/jbc.M413724200. Epub 2005 Jan 5.

Abstract

Multiple ligand co-recognition of 3'-sulfogalactosylceramide (SGC) and sulfotyrosine initiated the comparison of SGC and sulfotyrosine and, subsequently, phosphotyrosine (pY) binding. SGC is a receptor for ligands involved in cell adhesion/microbial pathology. pY forms a Src homology domain 2 recognition motif in intracellular signaling. Using hsp70, anti-SGC, and anti-pY antibodies, ligand binding is retained following phosphate/sulfate and tyrosine/galactose substitution in SGC and sulfate/phosphate exchange in pY. Remarkable lipid-dependent binding to phosphatidylethanolamine-conjugated sulfotyrosine suggests "microenvironmental" modulation of sulfotyrosine-containing receptors, similar to glycosphingolipids. Based on an aryl substrate-bound co-crystal of arylsulfatase A, a sulfogalactose and phosphotyrosine esterase, modeling provides a solvation basis for co-recognition. c-Src/Src homology domain 2:SGC/phosphogalactosylceramide binding confirms our hypothesis, heralding a carbohydrate-based approach to regulation of phosphotyrosine-mediated recognition.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Motifs
  • Binding Sites
  • Carbohydrate Conformation
  • Cell Adhesion
  • Cerebroside-Sulfatase / chemistry
  • Chromatography, Thin Layer
  • Cloning, Molecular
  • Crystallography, X-Ray
  • DNA, Complementary / metabolism
  • Galactose / chemistry*
  • Galactose / metabolism
  • Glycosphingolipids / chemistry*
  • HSP70 Heat-Shock Proteins / chemistry
  • Humans
  • Hydrogen Bonding
  • Leukocytes, Mononuclear / metabolism
  • Ligands
  • Models, Chemical
  • Models, Molecular
  • Phosphates / chemistry
  • Phosphotyrosine / chemistry*
  • Protein Binding
  • Protein Conformation
  • Protein Structure, Tertiary
  • Signal Transduction
  • Sulfates / chemistry
  • Tyrosine / chemistry
  • src Homology Domains

Substances

  • DNA, Complementary
  • Glycosphingolipids
  • HSP70 Heat-Shock Proteins
  • Ligands
  • Phosphates
  • Sulfates
  • Phosphotyrosine
  • Tyrosine
  • Cerebroside-Sulfatase
  • Galactose