The first example of solvothermally synthesized thioantimonates(V) with ethylenediamine coordinated lanthanide(III): [Sm(en)4]SbS4 x 0.5en and [Sm(en)3(H2O)(micro-SbS4)]infinity

Ding-xian Jia; Qin-Yu Zhu; Jie Dai; Wen Lu; Wen-Juan Guo

doi:10.1021/ic0484957

The first example of solvothermally synthesized thioantimonates(V) with ethylenediamine coordinated lanthanide(III): [Sm(en)4]SbS4 x 0.5en and [Sm(en)3(H2O)(micro-SbS4)]infinity

Inorg Chem. 2005 Feb 21;44(4):819-21. doi: 10.1021/ic0484957.

Authors

Ding-xian Jia¹, Qin-Yu Zhu, Jie Dai, Wen Lu, Wen-Juan Guo

Affiliation

¹ Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P R China.

PMID: 15859251
DOI: 10.1021/ic0484957

Abstract

Under mild solvothermal conditions two novel thioantimonates(V) [Sm(en)4]SbS4 x 0.5en (1) and [Sm(en)3(H2O)(micro-SbS4)]infinity (2) were synthesized; the structure of 1 contains discrete [Sm(en)4]3+ and [SbS4]3 ions, while 2 consists of neutral [Sm(en)3(H2O) (micro-SbS4)] one-dimensional chains.