A new cell for the study of in situ chemical reactions using X-ray absorption spectroscopy

J Synchrotron Radiat. 2005 Jul;12(Pt 4):499-505. doi: 10.1107/S090904950501143X. Epub 2005 Jun 15.

Abstract

An in situ cell for reductive and oxidative treatments at different temperatures that allows the possibility of recording data as a function of temperature has been designed and constructed for X-ray absorption experiments at the GILDA beamline BM08 of ESRF. The cell is linked to a mass quadrupole spectrometer providing control of the reaction gases and monitoring of the products. The apparatus allows measurements to be performed both in transmission and fluorescence geometry. The cell was tested by studying the CO oxidation reaction promoted by a Pt/ceria-zirconia-supported catalyst. The CO(2) yield is correlated with the structural results confirming the existence of a strong metal-support interaction between the Pt metal clusters and the ceria-zirconia support.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon Dioxide / analysis*
  • Carbon Dioxide / chemistry
  • Catalysis
  • Flow Injection Analysis / instrumentation*
  • Flow Injection Analysis / methods
  • Oxidation-Reduction
  • Oxygen / analysis*
  • Oxygen / chemistry
  • Platinum / chemistry
  • Specimen Handling / instrumentation*
  • Specimen Handling / methods
  • Spectrometry, X-Ray Emission / instrumentation*
  • Spectrometry, X-Ray Emission / methods
  • Temperature
  • X-Ray Diffraction / instrumentation*
  • X-Ray Diffraction / methods
  • Zirconium / chemistry

Substances

  • Carbon Dioxide
  • Platinum
  • Zirconium
  • zirconium oxide
  • Oxygen