Synthesis of amorphous carbon nanoparticles and carbon encapsulated metal nanoparticles in liquid benzene by an electric plasma discharge in ultrasonic cavitation field

Ultrason Sonochem. 2006 Jan;13(1):6-12. doi: 10.1016/j.ultsonch.2004.12.006. Epub 2005 Feb 25.

Abstract

A newly-developed method permits an electric plasma discharge to occur with relatively low electric power in insulating organic solutions due to the presence of an ultrasonic cavitation. A stable electric plasma could be generated in an ultrasonic cavitation field containing a thousand tiny activated bubbles, in which the electric conductivity could be improved due to formed radicals and free electrons, using copper electrodes and a titanium ultrasonic horn. This method allowed us to synthesize pyrolytic amorphous carbon nanoparticles smaller than about 30 nm in diameter from benzene liquid. In addition, we synthesized TiC nanoparticles about 50-150 nm in size, and copper nanoparticles smaller than 10 nm, which were encapsulated in multilayered graphite cages. Finally, we used GC-MS and MALDI-TOF-MS to observe and analyze the polymerized compounds and the degree of polymerization of the benzene liquid after the plasma treatment.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzene / chemistry*
  • Coated Materials, Biocompatible / chemistry
  • Coated Materials, Biocompatible / radiation effects
  • Crystallization / methods*
  • Electrochemistry / methods*
  • Hot Temperature*
  • Metals / chemistry*
  • Nanotubes, Carbon / chemistry*
  • Nanotubes, Carbon / radiation effects
  • Nanotubes, Carbon / ultrastructure
  • Particle Size
  • Solutions
  • Ultrasonics*

Substances

  • Coated Materials, Biocompatible
  • Metals
  • Nanotubes, Carbon
  • Solutions
  • Benzene