Severe acute respiratory syndrome coronavirus papain-like protease: structure of a viral deubiquitinating enzyme

Proc Natl Acad Sci U S A. 2006 Apr 11;103(15):5717-22. doi: 10.1073/pnas.0510851103. Epub 2006 Mar 31.

Abstract

Replication of severe acute respiratory syndrome (SARS) coronavirus (SARS-CoV) requires proteolytic processing of the replicase polyprotein by two viral cysteine proteases, a chymotrypsin-like protease (3CLpro) and a papain-like protease (PLpro). These proteases are important targets for development of antiviral drugs that would inhibit viral replication and reduce mortality associated with outbreaks of SARS-CoV. In this work, we describe the 1.85-A crystal structure of the catalytic core of SARS-CoV PLpro and show that the overall architecture adopts a fold closely resembling that of known deubiquitinating enzymes. Key features, however, distinguish PLpro from characterized deubiquitinating enzymes, including an intact zinc-binding motif, an unobstructed catalytically competent active site, and the presence of an intriguing, ubiquitin-like N-terminal domain. To gain insight into the active-site recognition of the C-terminal tail of ubiquitin and the related LXGG motif, we propose a model of PLpro in complex with ubiquitin-aldehyde that reveals well defined sites within the catalytic cleft that help to account for strict substrate-recognition motifs.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Binding Sites
  • Coronavirus 3C Proteases
  • Crystallography, X-Ray
  • Cysteine Endopeptidases / chemistry*
  • Models, Molecular
  • Papain / metabolism*
  • Peptide Hydrolases / metabolism*
  • Protein Structure, Secondary
  • Severe acute respiratory syndrome-related coronavirus / enzymology*
  • Ubiquitin / metabolism*
  • Viral Proteins / chemistry*

Substances

  • Ubiquitin
  • Viral Proteins
  • Peptide Hydrolases
  • Cysteine Endopeptidases
  • Papain
  • Coronavirus 3C Proteases

Associated data

  • PDB/2FE8