Development of antithrombotic miniribozymes that target peripheral tryptophan hydroxylase

Mol Cell Biochem. 2007 Jan;295(1-2):205-15. doi: 10.1007/s11010-006-9290-8. Epub 2006 Aug 22.

Abstract

Serotonin is not only a neurotransmitter in the central nervous system, but also a ubiquitous hormone in the periphery involved in vasoconstriction and platelet function. Tryptophan hydroxylase is the rate-limiting enzyme in serotonin biosynthesis. By gene targeting, we have shown that serotonin is synthesized independently by two different tryptophan hydroxylase isoenzymes in peripheral tissues and neurons and identified a neuronal tryptophan hydroxylase isoform. Mice deficient in peripheral tryptophan hydroxylase (TPH1) and serotonin exhibit a reduced risk of thrombosis and thromboembolism. Therefore, we designed several antitph1 hammerhead miniribozymes and tested their cleavage activity against short synthetic Tph1 RNA substrates. In vitro cleavage studies demonstrated site-specific cleavage of Tph1 mRNA that was dependent on substrate/miniribozyme ratio and duration of exposure to miniribozyme. Interestingly, we detected different in vitro cleavage rates after we had cloned the miniribozymes into tRNA expression constructs, and found one with a high cleavage rate. We also demonstrated that this active tRNA-miniribozyme chimera is capable of selectively cleaving native Tph1 mRNA in vivo, with concomitant downregulation of the serotonin biosynthesis. Therefore, this Tph1-specific miniribozyme may provide a novel and effective form of gene therapy that may be applicable to a variety of thrombotic diseases.

MeSH terms

  • Animals
  • Base Sequence
  • Fibrinolytic Agents / pharmacology*
  • Gene Expression Regulation, Enzymologic / drug effects
  • Mice
  • Molecular Sequence Data
  • Nucleic Acid Conformation / drug effects
  • RNA, Catalytic / pharmacology*
  • RNA, Messenger / chemistry
  • RNA, Transfer / chemistry
  • Thermodynamics
  • Tryptophan Hydroxylase / antagonists & inhibitors*
  • Tryptophan Hydroxylase / genetics
  • Tryptophan Hydroxylase / metabolism

Substances

  • Fibrinolytic Agents
  • RNA, Catalytic
  • RNA, Messenger
  • RNA, Transfer
  • Tryptophan Hydroxylase