Abstract
Isotopic desymmetrisation, as well as (stereo)chemical correlation, has illuminated significant aspects of the sigma-pi-sigma mechanism of copper-catalysed allylic substitution reactions: an enantiospecific and regioselective access to alpha-chiral silanes is presented.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Copper / chemistry*
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Molecular Structure
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Organometallic Compounds / chemistry*
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Silanes / chemical synthesis*
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Silanes / chemistry
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Stereoisomerism
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Zinc / chemistry*
Substances
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Organometallic Compounds
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Silanes
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Copper
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Zinc