Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions

Chem Commun (Camb). 2007 Mar 7:(9):936-8. doi: 10.1039/b618156b. Epub 2007 Jan 30.

Abstract

Radical cascades employing (dichloromethyl)dimethylsilyl ethers as both a point of radical initiation and termination, allow efficient entry to fused polycyclic cyclopropanes, and are also suitable for the design of other radical processes terminated by beta-elimination of chloride.