Quercetin protects human hepatocytes from ethanol-derived oxidative stress by inducing heme oxygenase-1 via the MAPK/Nrf2 pathways

J Hepatol. 2007 Aug;47(2):253-61. doi: 10.1016/j.jhep.2007.02.008. Epub 2007 Mar 7.

Abstract

Background/aims: Flavonoids, including quercetin, have been reported to have potent hepatoprotective effects, which may be associated with HO-1 induction. However, since the effect and signaling pathway of quercetin involved in HO-1 induction against alcoholic liver damage are still not fully understood, this is the target of the present study.

Methods: Human hepatocytes were incubated with ethanol (100 mM) and quercetin (10-200 microM), and cellular damage and HO-1 activity were measured. Nrf2 expression in cytosolic and nuclear fractions was studied following the incubation with MAPK inhibitor(s).

Results: Ethanol exposure resulted in a sustained glutathione depletion, malondialdehyde elevation, and evident release of cellular LDH and AST. Quercetin exerted a dose-dependent protective effect against alcoholic oxidative stress, and increased the EC50 of ethanol by approx. 40%, which is parallel to HO-1 induction with quercetin. Zinc protoporphyrin-9 abrogated the protective effect and dramatically enhanced ethanol cytotoxicity. SB203580 (p38 inhibitor) and especially PD98059 (ERK inhibitor) blocked quercetin-derived HO-1 induction and Nrf2 translocation, and subsequently inhibited the quercetin-related protection.

Conclusions: HO-1 up-regulation by quercetin protected human hepatocytes from ethanol-induced oxidative stress. Among MAPK signaling pathways, p38 and ERK mediated quercetin-derived Nrf2 translocation into nuclei and subsequent induction of HO-1 activity, and the latter showed a stronger mediating effect.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biological Transport / drug effects
  • Cells, Cultured
  • Cytoprotection
  • Dose-Response Relationship, Drug
  • Ethanol / pharmacology*
  • Heme Oxygenase-1 / biosynthesis*
  • Hepatocytes / drug effects*
  • Hepatocytes / metabolism*
  • Humans
  • Mitogen-Activated Protein Kinases / metabolism*
  • NF-E2-Related Factor 2 / metabolism*
  • Oxidative Stress / drug effects*
  • Quercetin / administration & dosage
  • Quercetin / pharmacology*
  • Signal Transduction / physiology

Substances

  • NF-E2-Related Factor 2
  • Ethanol
  • Quercetin
  • Heme Oxygenase-1
  • Mitogen-Activated Protein Kinases