"O-acyl isopeptide method" for peptide synthesis: synthesis of forty kinds of "O-acyl isodipeptide unit" Boc-Ser/Thr(Fmoc-Xaa)-OH

Org Biomol Chem. 2007 Jun 7;5(11):1720-30. doi: 10.1039/b702284k. Epub 2007 Apr 25.

Abstract

The O-acyl isopeptide method has recently received attention as an efficient synthetic method for peptides. Herein, forty kinds of "O-acyl isodipeptide unit" Boc-Ser/Thr(Fmoc-Xaa)-OH (1-40) were effectively synthesized in two-steps without epimerization. The O-acyl isodipeptide units are important building blocks to enable the routine use of the O-acyl isopeptide method.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Chemistry, Organic / methods*
  • Chromatography, High Pressure Liquid
  • Dipeptides / analysis
  • Dipeptides / chemical synthesis*
  • Dipeptides / chemistry
  • Esterification
  • Influenza A virus / chemistry
  • Isomerism
  • Molecular Sequence Data
  • Oligopeptides / analysis
  • Oligopeptides / chemical synthesis*
  • Oligopeptides / chemistry

Substances

  • Dipeptides
  • Oligopeptides