Selection of a water-extractable phosphorus test for manures and biosolids as an indicator of runoff loss potential

J Environ Qual. 2007 Jul 17;36(5):1357-67. doi: 10.2134/jeq2006.0450. Print 2007 Sep-Oct.

Abstract

The correlation of runoff phosphorus (P) with water-extractable phosphorus (WEP) in land-applied manures and biosolids has spurred wide use of WEP as a water quality indicator. Land managers, planners, and researchers need a common WEP protocol to consistently use WEP in nutrient management. Our objectives were to (i) identify a common WEP protocol with sufficient accuracy and precision to be adopted by commercial testing laboratories and (ii) confirm that the common protocol is a reliable index of runoff P. Ten laboratories across North America evaluated alternative protocols with an array of manure and biosolids samples. A single laboratory analyzed all samples and conducted a separate runoff study with the manures and biosolids. Extraction ratio (solution:solids) was the most important factor affecting WEP, with WEP increasing from 10:1 to 100:1 and increasing from 100:1 to 200:1. When WEP was measured by a single laboratory, correlations with runoff P from packed soil boxes amended with manure and biosolids ranged from 0.79 to 0.92 across all protocol combinations (extraction ratio, filtration method, and P determination method). Correlations with P in runoff were slightly lower but significant when WEP was measured by the 10 labs (r=0.56-0.86). Based on laboratory repeatability and water quality evaluation criteria, we recommend the following common protocol: 100:1 extraction ratio; 1-h shaking and centrifuge 10 min at 1500xg (filter with Whatman #1 paper if necessary); and determining P by inductively coupled plasma-atomic emission spectrometry or colorimetric methods.

Publication types

  • Evaluation Study

MeSH terms

  • Agriculture
  • Animals
  • Conservation of Natural Resources
  • Environmental Monitoring / methods*
  • Manure / analysis*
  • Phosphorus / analysis*
  • Phosphorus / isolation & purification
  • Rain
  • Water / chemistry*
  • Water Pollution / prevention & control

Substances

  • Manure
  • Water
  • Phosphorus