High-performance liquid chromatographic evaluation of Med 15 and its metabolites Med 5 and tolmetin in rat plasma

J Chromatogr. 1991 Aug 16;553(1-2):81-6. doi: 10.1016/s0021-9673(01)88475-2.

Abstract

A simple and reliable high-performance liquid chromatographic method is described for the quantitative analysis of the new non-steroidal anti-inflammatory agent Med 15 and its metabolites Med 5 and tolmetin in rat plasma. After selective extraction the three analytes and an internal standard (p-phenyl-phenol) were separated on a reversed-phase Ultrasphere 5 micron column using potassium dihydrogenphosphate (0.05 M)-acetonitrile (52:48) (pH 4.7) as the mobile phase. The analytes were detected at 313 nm; the sensitivity of the method proved to be 0.05 microgram/ml for all three compounds. The method has been applied to investigate Med 15 pharmacokinetics in rats.

MeSH terms

  • Animals
  • Anti-Inflammatory Agents, Non-Steroidal / blood*
  • Chromatography, Gas
  • Chromatography, High Pressure Liquid
  • Glycine / analogs & derivatives*
  • Glycine / blood
  • Male
  • Mass Spectrometry
  • Pyrroles / blood*
  • Rats
  • Rats, Inbred Strains
  • Spectrophotometry, Ultraviolet
  • Tolmetin / analogs & derivatives*
  • Tolmetin / blood*

Substances

  • Anti-Inflammatory Agents, Non-Steroidal
  • Pyrroles
  • ST 679
  • tolmetin glycinamide
  • Tolmetin
  • Glycine