Synthesis, structure and emission properties of spirocyclic benzofuranones and dihydroindolones: a domino insertion-coupling-isomerization- Diels-Alder approach to rigid fluorophores

Chemistry. 2008;14(2):529-47. doi: 10.1002/chem.200700759.

Abstract

An alkynoyl ortho-iodo phenolester or alkynoyl ortho-iodo anilides and propargyl allyl ethers react under Sonogashira coupling conditions in the sense of an insertion-coupling-isomerization-Diels-Alder hetero domino reaction to furnish (tetrahydroisobenzofuran)-spirobenzofuranones and -spirodihydroindolones in good yields. Many representatives can be crystallized and single crystal structure analyses display steric and electronic substituent effects on the torsional angles of the terminal (hetero)aryl groups and the central cis,trans-butadiene fragment. DFT computations reveal that in the final pericyclic step the Diels-Alder termination is by far thermodynamically and kinetically favored over a possible Claisen rearrangement. Compounds of this new class of spirocyclic compounds possess large Stokes shifts and fluoresce intensively with blue over green to orange colors. As a consequence of the spirocyclic rigidity fluorescence lifetimes and quantum yields are rather high in some cases.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzofurans* / chemical synthesis
  • Benzofurans* / chemistry
  • Computer Simulation
  • Crystallography, X-Ray
  • Cyclization
  • Fluorescence
  • Indoles* / chemical synthesis
  • Indoles* / chemistry
  • Macrocyclic Compounds* / chemical synthesis
  • Macrocyclic Compounds* / chemistry
  • Magnetic Resonance Spectroscopy / methods
  • Models, Chemical
  • Models, Molecular
  • Molecular Structure
  • Quantum Theory
  • Spectrophotometry, Ultraviolet / methods
  • Spiro Compounds* / chemical synthesis
  • Spiro Compounds* / chemistry
  • Stereoisomerism

Substances

  • Benzofurans
  • Indoles
  • Macrocyclic Compounds
  • Spiro Compounds