Degradation of 1-butyl-3-methylimidazolium chloride ionic liquid in a Fenton-like system

J Hazard Mater. 2008 Jun 15;154(1-3):893-900. doi: 10.1016/j.jhazmat.2007.10.104. Epub 2007 Nov 7.

Abstract

The study examined the usefulness of a Fenton-like system for the degradation of ionic liquid residues in water. The ionic liquid was oxidized in a dilute aqueous solution of 1-butyl-3-methylimidazolium chloride (bmimCl). The ionic liquid decomposes readily and rapidly in aqueous solution by chemical degradation in a Fenton-like system. Under chosen conditions the initial bmimCl solution was reduced by a factor of 0.973 within 90 min. Additional results showed that bmimCl degradations in a Fenton-like system in excess H2O2 could be interpreted as a combined oxidation-reduction mechanism. Preliminary investigations of the mechanism of such degradations have indicated that initial OH* radicals can attack any one of the three carbon atoms on the imidazolium ring. The intermediates of this reaction may be mono- di- or amino- carboxylic acids.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carboxylic Acids / chemistry
  • Hydrogen Peroxide / chemistry*
  • Hydrogen-Ion Concentration
  • Imidazoles / chemistry*
  • Iron / chemistry*
  • Oxidants / chemistry*
  • Oxidation-Reduction
  • Water Pollutants, Chemical / chemistry*
  • Water Purification / methods

Substances

  • Carboxylic Acids
  • Imidazoles
  • Oxidants
  • Water Pollutants, Chemical
  • 1-butyl-3-methylimidazolium chloride
  • Hydrogen Peroxide
  • Iron