Ligand-directed nanobialys as theranostic agent for drug delivery and manganese-based magnetic resonance imaging of vascular targets

J Am Chem Soc. 2008 Jul 23;130(29):9186-7. doi: 10.1021/ja801482d. Epub 2008 Jun 24.

Abstract

Although gadolinium has been the dominant paramagnetic metal for MR paramagnetic contrast agents, the recent association of this lanthanide with nephrogenic systemic fibrosis, an untreatable disease, has spawned renewed interest in alternative metals for MR molecular imaging. We have developed a self-assembled, manganese(III)-labeled nanobialys (1), a toroidal-shaped MR theranostic nanoparticle. In this report, Mn(III) nanobialys are characterized as MR molecular imaging agents for targeted detection of fibrin, a major biochemical feature of thrombus. A complementary ability of nanobialys to incorporate chemotherapeutic compounds with greater than 98% efficiency and to retain more than 80% of these drugs after infinite sink dissolution, point to the theranostic potential of this platform technology.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Biotin / chemistry
  • Camptothecin / administration & dosage
  • Camptothecin / chemistry
  • Doxorubicin / administration & dosage
  • Doxorubicin / chemistry
  • Drug Delivery Systems / methods*
  • Fibrin / analysis
  • Fibrin / chemistry
  • Humans
  • Magnetic Resonance Angiography / methods*
  • Manganese / chemistry*
  • Micelles
  • Microscopy, Atomic Force
  • Nanoparticles / chemistry*
  • Organometallic Compounds / chemistry

Substances

  • Micelles
  • Organometallic Compounds
  • Manganese
  • Biotin
  • Doxorubicin
  • Fibrin
  • Camptothecin