Oxidative demethylation of 3-methylthymine and 3-methyluracil in single-stranded DNA and RNA by mouse and human FTO

FEBS Lett. 2008 Oct 15;582(23-24):3313-9. doi: 10.1016/j.febslet.2008.08.019. Epub 2008 Sep 5.

Abstract

The human obesity susceptibility gene, FTO, encodes a protein that is homologous to the DNA repair AlkB protein. The AlkB family proteins utilize iron(II), alpha-ketoglutarate (alpha-KG) and dioxygen to perform oxidative repair of alkylated nucleobases in DNA and RNA. We demonstrate here the oxidative demethylation of 3-methylthymine (3-meT) in single-stranded DNA (ssDNA) and 3-methyluracil (3-meU) in single-stranded RNA (ssRNA) by recombinant human FTO protein in vitro. Both human and mouse FTO proteins preferentially repair 3-meT in ssDNA over other base lesions tested. They showed negligible activities against 3-meT in double-stranded DNA (dsDNA). In addition, these two proteins can catalyze the demethylation of 3-meU in ssRNA with a slightly higher efficiency over that of 3-meT in ssDNA, suggesting that methylated RNAs are the preferred substrates for FTO.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alpha-Ketoglutarate-Dependent Dioxygenase FTO
  • Animals
  • DNA Repair
  • DNA, Single-Stranded / chemistry
  • DNA, Single-Stranded / metabolism*
  • Humans
  • Methylation
  • Mice
  • Mixed Function Oxygenases
  • Oxidation-Reduction
  • Oxo-Acid-Lyases / chemistry
  • Oxo-Acid-Lyases / metabolism*
  • Proteins / chemistry
  • Proteins / metabolism*
  • RNA / metabolism*
  • Recombinant Proteins / chemistry
  • Substrate Specificity
  • Thymine / analogs & derivatives*
  • Thymine / chemistry
  • Thymine / metabolism
  • Uracil / analogs & derivatives*
  • Uracil / chemistry
  • Uracil / metabolism

Substances

  • DNA, Single-Stranded
  • Proteins
  • Recombinant Proteins
  • Uracil
  • 3-methyluracil
  • RNA
  • Mixed Function Oxygenases
  • FTO protein, mouse
  • Alpha-Ketoglutarate-Dependent Dioxygenase FTO
  • FTO protein, human
  • Oxo-Acid-Lyases
  • Thymine
  • 3-methylthymine