Synthesis of isoindolobenzazepine alkaloids based on radical reactions or Pd(0)-catalyzed reactions

J Org Chem. 2009 Aug 7;74(15):5486-95. doi: 10.1021/jo900311g.

Abstract

Methods for synthesis of a ring system characteristic of isoindolobenzazepine alkaloids were studied. Synthesis of lennoxamine and a formal synthesis of chelenine were accomplished in a short route via radical or Pd(0)-catalyzed cyclization as the key step. An altenative approach based on a radical migration of a cyano group or Pd(0)-catalyzed carbonylation was also developed for both alkaloids.

MeSH terms

  • Alkaloids / chemical synthesis*
  • Alkaloids / chemistry
  • Benzazepines / chemical synthesis*
  • Benzazepines / chemistry
  • Catalysis
  • Cyclization
  • Free Radicals / chemical synthesis
  • Free Radicals / chemistry
  • Molecular Structure
  • Palladium / chemistry*
  • Stereoisomerism

Substances

  • Alkaloids
  • Benzazepines
  • Free Radicals
  • Palladium