Evaluation of a 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid-conjugated bombesin-based radioantagonist for the labeling with single-photon emission computed tomography, positron emission tomography, and therapeutic radionuclides

Clin Cancer Res. 2009 Aug 15;15(16):5240-9. doi: 10.1158/1078-0432.CCR-08-3145. Epub 2009 Aug 11.

Abstract

Purpose: G protein-coupled receptor agonists are being used as radiolabeled vectors for in vivo localization and therapy of tumors. Recently, somatostatin-based antagonists were shown to be superior to agonists. Here, we compare the new [111In/68Ga]-labeled bombesin-based antagonist RM1 with the agonist [111In]-AMBA for targeting the gastrin-releasing peptide receptor (GRPR).

Experimental design: IC50, Kd values, and antagonist potency were determined using PC-3 and HEK-GRPR cells. Biodistribution and imaging studies were done in nude mice transplanted with the PC-3 tumor. The antagonist potency was assessed by evaluating the effects on calcium release and on receptor internalization monitored by immunofluorescence microscopy.

Results: The IC50 value of [(nat)In]-RM1 was 14 +/- 3.4 nmol/L. [(nat/111)In]-RM1 was found to bind to the GRPR with a Kd of 8.5 +/- 2.7 nmol/L compared with a Kd of 0.6 +/- 0.3 nmol/L of [111In]-AMBA. A higher maximum number of binding site value was observed for [111In]-RM1 (2.4 +/- 0.2 nmol/L) compared with [111In]-AMBA (0.7 +/- 0.1 nmol/L). [(nat)Lu]-AMBA is a potent agonist in the immunofluorescence-based internalization assay, whereas [(nat)In]-RM1 is inactive alone but efficiently antagonizes the bombesin effect. These data are confirmed by the calcium release assay. The pharmacokinetics showed a superiority of the radioantagonist with regard to the high tumor uptake (13.4 +/- 0.8% IA/g versus 3.69 +/- 0.75% IA/g at 4 hours after injection. as well as to all tumor-to-normal tissue ratios.

Conclusion: Despite their relatively low GRPR affinity, the antagonists [111In/68Ga]-RM1 showed superior targeting properties compared with [111In]-AMBA. As found for somatostatin receptor-targeting radiopeptides, GRP-based radioantagonists seem to be superior to radioagonists for in vivo imaging and potentially also for targeted radiotherapy of GRPR-positive tumors.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Bombesin / chemistry*
  • Cells, Cultured
  • Drug Delivery Systems / methods
  • Female
  • Gallium Radioisotopes / chemistry
  • Gallium Radioisotopes / pharmacokinetics
  • Gallium Radioisotopes / therapeutic use
  • Heterocyclic Compounds, 1-Ring / chemistry*
  • Humans
  • Indium Radioisotopes / chemistry
  • Indium Radioisotopes / pharmacokinetics
  • Indium Radioisotopes / therapeutic use
  • Mice
  • Mice, Nude
  • Models, Biological
  • Neoplasms / diagnostic imaging*
  • Neoplasms / metabolism
  • Oligopeptides / chemistry
  • Oligopeptides / pharmacokinetics
  • Positron-Emission Tomography / methods*
  • Radioisotopes / chemistry
  • Radioisotopes / pharmacokinetics
  • Radioisotopes / therapeutic use*
  • Receptors, Bombesin / agonists*
  • Receptors, Bombesin / antagonists & inhibitors*
  • Receptors, Bombesin / metabolism
  • Receptors, G-Protein-Coupled / agonists
  • Receptors, G-Protein-Coupled / antagonists & inhibitors
  • Receptors, G-Protein-Coupled / metabolism
  • Tomography, Emission-Computed, Single-Photon / methods*
  • Transplantation, Heterologous

Substances

  • DO3A-CH2CO-G-4-aminobenzoyl-Q-W-A-V-G-H-L-M-NH2
  • Gallium Radioisotopes
  • Heterocyclic Compounds, 1-Ring
  • Indium Radioisotopes
  • Oligopeptides
  • Radioisotopes
  • Receptors, Bombesin
  • Receptors, G-Protein-Coupled
  • 1,4,7,10-tetraazacyclododecane- 1,4,7,10-tetraacetic acid
  • Bombesin