Strong hydrogen binding within a 3D microporous metal-organic framework

Di-Chang Zhong; Jian-Bin Lin; Wen-Guan Lu; Long Jiang; Tong-Bu Lu

doi:10.1021/ic900968d

Strong hydrogen binding within a 3D microporous metal-organic framework

Inorg Chem. 2009 Sep 21;48(18):8656-8. doi: 10.1021/ic900968d.

Authors

Di-Chang Zhong¹, Jian-Bin Lin, Wen-Guan Lu, Long Jiang, Tong-Bu Lu

Affiliation

¹ MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, and School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

PMID: 19702250
DOI: 10.1021/ic900968d

Abstract

A 3D microporous cadmium(II) metal-organic framework based on 1H-tetrazole exhibits strong hydrogen binding with an initial enthalpy of adsorption of 13.3 kJ/mol, due to the smaller pore sizes and the high hydrogen binding affinity of the tetrazolyl-ring-decorated inner surface of the pores.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Cadmium / chemistry*
Crystallography, X-Ray
Hydrogen / chemistry*
Microchemistry
Models, Molecular
Organometallic Compounds / chemistry*
Porosity
Tetrazoles / chemistry
Thermodynamics

Substances

Organometallic Compounds
Tetrazoles
Cadmium
1H-tetrazole
Hydrogen