Abstract
Due to the importance of allylamines in organic synthesis, the synthesis of reagents as potent precursors of aminofluoroolefins is reported from functionalized benzothiazolylsulfones. The key intermediate, a fluorovinyl sulfone, was prepared and functionalized by addition of aliphatic, aromatic amines and amino acid alkyl esters through an aza-Michael addition reaction.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry
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Allylamine / analogs & derivatives
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Allylamine / chemistry
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Amines / chemical synthesis*
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Amines / chemistry
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Amino Acids / chemistry
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Aza Compounds / chemistry
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Benzothiazoles / chemical synthesis*
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Benzothiazoles / chemistry
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Esters / chemistry
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Hydrocarbons, Fluorinated / chemical synthesis*
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Hydrocarbons, Fluorinated / chemistry
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Models, Chemical
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Sulfones / chemical synthesis*
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Sulfones / chemistry
Substances
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Alkenes
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Amines
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Amino Acids
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Aza Compounds
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Benzothiazoles
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Esters
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Hydrocarbons, Fluorinated
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Sulfones
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Allylamine