Eicosanuclear cluster [Cu(13)W(7)] of copper-octacyanotungstate bimetallic assembly: synthesis, structure, and magnetic properties

Jun Wang; Zai-Chao Zhang; Hui-Sheng Wang; Ling-Chen Kang; Hong-Bo Zhou; You Song; Xiao-Zeng You

doi:10.1021/ic100282w

Eicosanuclear cluster [Cu(13)W(7)] of copper-octacyanotungstate bimetallic assembly: synthesis, structure, and magnetic properties

Inorg Chem. 2010 Apr 5;49(7):3101-3. doi: 10.1021/ic100282w.

Authors

Jun Wang¹, Zai-Chao Zhang, Hui-Sheng Wang, Ling-Chen Kang, Hong-Bo Zhou, You Song, Xiao-Zeng You

Affiliation

¹ State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou Road 22, Nanjing 210093, People's Republic of China.

PMID: 20218652
DOI: 10.1021/ic100282w

Abstract

Octacyanotungstate(V) reacts with Cu(NO(3))(2).2H(2)O and 1,4,7-trimethyl-1,4,7-triazacyclononane in methanol, resulting in an eicosanuclear cluster [Cu(13)W(7)], which shows a diamondoid shape with a Tolkowsky cut and bears intracluster ferromagnetic coupling.