A safe and practical procedure for global deprotection of oligoribonucleotides

J Org Chem. 2010 Aug 6;75(15):5305-7. doi: 10.1021/jo100648e.

Abstract

We report a practical global deprotection of RNA 2'-O-tert-butyldimethylsilyl (TBS) ethers using commercially available aqueous NH(4)F. The procedure is applicable to both 96-well plate format and large-scale production of RNA. This improved procedure provides a safe, mild, and cost-effective alternative to highly hazardous Et(3)N x 3 HF, a reagent commonly used in the routine synthesis of RNA.

MeSH terms

  • Ammonium Compounds
  • Chromatography, High Pressure Liquid
  • Fluorides / chemistry
  • Oligoribonucleotides / chemistry*
  • Quaternary Ammonium Compounds / chemistry
  • Spectrometry, Mass, Electrospray Ionization
  • Spectrophotometry, Ultraviolet

Substances

  • Ammonium Compounds
  • Oligoribonucleotides
  • Quaternary Ammonium Compounds
  • ammonium fluoride
  • Fluorides