Tuning shades of white light with multi-color quantum-dot-quantum-well emitters based on onion-like CdSe-ZnS heteronanocrystals

Nanotechnology. 2008 Aug 20;19(33):335203. doi: 10.1088/0957-4484/19/33/335203. Epub 2008 Jul 7.

Abstract

We present white light generation controlled and tuned by multi-color quantum-dot-quantum-well emitters made of onion-like CdSe/ZnS/CdSe core/shell/shell heteronanocrystals integrated on InGaN/GaN light-emitting diodes (LEDs). We demonstrate hybrid white LEDs with (x, y) tristimulus coordinates tuned from (0.26, 0.33) to (0.37, 0.36) and correlated color temperatures from 27 413 to 4192 K by controlling the number of their integrated red-green-emitting heteronanocrystals. We investigate the modification of in-film emission from these multi-layered heteronanocrystals with respect to their in-solution emission, which plays a significant role in hybrid LED applications. Our proof-of-principle experiments indicate that these complex heteronanocrystals hold promise for use as nanoluminophors in future hybrid white LEDs.