IgY14 and SuperMix immunoaffinity separations coupled with liquid chromatography-mass spectrometry for human plasma proteomics biomarker discovery

Methods. 2012 Feb;56(2):246-53. doi: 10.1016/j.ymeth.2011.09.001. Epub 2011 Sep 10.

Abstract

Interest in the application of advanced proteomics technologies to human blood plasma- or serum-based clinical samples for the purpose of discovering disease biomarkers continues to grow; however, the enormous dynamic range of protein concentrations in these types of samples (often >10 orders of magnitude) represents a significant analytical challenge, particularly for detecting low-abundance candidate biomarkers. In response, immunoaffinity separation methods for depleting multiple high- and moderate-abundance proteins have become key tools for enriching low-abundance proteins and enhancing detection of these proteins in plasma proteomics. Herein, we describe IgY14 and tandem IgY14-Supermix separation methods for removing 14 high-abundance and up to 60 moderate-abundance proteins, respectively, from human blood plasma and highlight their utility when combined with liquid chromatography-tandem mass spectrometry for interrogating the human plasma proteome.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.
  • Review

MeSH terms

  • Biomarkers / analysis
  • Biomarkers / blood
  • Blood Proteins / analysis*
  • Blood Proteins / chemistry
  • Blood Proteins / isolation & purification
  • Chromatography, Affinity / instrumentation
  • Chromatography, Affinity / methods*
  • Humans
  • Immunoassay / instrumentation
  • Immunoassay / methods*
  • Immunoglobulins / chemistry
  • Immunoglobulins / isolation & purification*
  • Mass Spectrometry / methods*
  • Proteome / analysis
  • Proteome / isolation & purification
  • Proteomics / methods*
  • Reproducibility of Results
  • Sensitivity and Specificity

Substances

  • Biomarkers
  • Blood Proteins
  • IgY
  • Immunoglobulins
  • Proteome