A new platinum-bromine cyclohexanediamine complex from the family of cancer cytostatics

Acta Crystallogr C. 2012 Dec;68(Pt 12):m340-3. doi: 10.1107/S0108270112044770. Epub 2012 Nov 9.

Abstract

Another new substance from the family of Pt-based coordination complexes with potential use in cancer chemotherapy has been synthesized, crystallized and structurally characterized. In this compound {systematic name cis-dibromido[(1R,2R)-cyclohexane-1,2-diamine-κ(2)N,N']platinum(II)}, cis-[PtBr(2)(C(6)H(14)N(2))], there are two molecules with very similar conformations in the asymmetric unit. The component species interact by way of N-H...Br and C-H...Br hydrogen bonds to give two-dimensional networks which lie parallel to the (100) plane.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antineoplastic Agents / chemical synthesis*
  • Antineoplastic Agents / chemistry*
  • Antineoplastic Agents / pharmacology
  • Crystallography, X-Ray
  • Cyclohexanes / chemistry*
  • Cytostatic Agents / chemical synthesis*
  • Cytostatic Agents / chemistry*
  • Cytostatic Agents / pharmacology
  • Diamines / chemistry*
  • Mice
  • Molecular Conformation
  • Neoplasms / chemistry*
  • Neoplasms / drug therapy
  • Organoplatinum Compounds / chemical synthesis*
  • Organoplatinum Compounds / chemistry*
  • Organoplatinum Compounds / pharmacology

Substances

  • Antineoplastic Agents
  • Cyclohexanes
  • Cytostatic Agents
  • Diamines
  • Organoplatinum Compounds
  • cis-dibromido((1R,2R)-cyclohexane-1,2-diamine-kappa(2)N,N')platinum(II)
  • Cyclohexane