Ortho/para ratio of H2O+ toward Sagittarius B2(M) revisited

J Phys Chem A. 2013 Oct 3;117(39):9766-9. doi: 10.1021/jp312364c. Epub 2013 Jun 6.

Abstract

The HIFI instrument aboard the Herschel satellite has allowed the observation and characterization of light hydrides, the building blocks of interstellar chemistry. In this article, we revisit the ortho/para ratio for H2O(+) toward the Sgr B2(M) cloud core. The line of sight toward this star forming region passes through several spiral arms and the gas in the Bar potential in the inner Galaxy. In contrast to earlier findings, which used fewer lines to constrain the ratio, we find a ratio of 3, which is uniformly consistent with high-temperature formation of the species. In view of the reactivity of this ion, this matches the expectations.