Regulation of ecto-apyrase CD39 (ENTPD1) expression by phosphodiesterase III (PDE3)

FASEB J. 2013 Nov;27(11):4419-28. doi: 10.1096/fj.13-234625. Epub 2013 Jul 30.

Abstract

The ectoenzyme CD39 suppresses thrombosis and inflammation by suppressing ATP and ADP to AMP. However, mechanisms of CD39 transcriptional and post-translational regulation are not well known. Here we show that CD39 levels are modulated by inhibition of phosphodiesterase 3 (PDE3). RAW macrophages and human umbilical vein endothelial cells (HUVECs) were treated with the PDE3 inhibitors cilostazol and milrinone, then analyzed using qRT-PCR, immunoprecipitation/Western blot, immunofluorescent staining, radio-thin-layer chromatography, a malachite green assay, and ELISA. HUVECs expressed elevated CD39 protein (2-fold [P<0.05] for cilostazol and 2.5-fold [P<0.01] for milrinone), while macrophage CD39 mRNA and protein were both elevated after PDE3 inhibition. HUVEC ATPase activity increased by 25% with cilostazol and milrinone treatment (P<0.05 and P<0.01, respectively), as did ADPase activity (47% and 61%, P<0.001). There was also a dose-dependent elevation of soluble CD39 after treatment with 8-Br-cAMP, with maximal elevation of 60% more CD39 present compared to controls (1 mM, P<0.001). Protein harvested after 8-Br-cAMP treatment showed that ubiquitination of CD39 was decreased by 43% compared to controls. A DMSO or PBS vehicle control was included for each experiment based on solubility of cilostazol, milrinone, and 8-Br-cAMP. These results indicate that PDE3 inhibition regulates endothelial CD39 at a post-translational level.

Keywords: cAMP; endothelium; vascular homeostasis.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • 8-Bromo Cyclic Adenosine Monophosphate / pharmacology
  • Adenosine Triphosphatases / genetics
  • Adenosine Triphosphatases / metabolism
  • Antigens, CD / genetics*
  • Apyrase / genetics*
  • Cilostazol
  • Cyclic Nucleotide Phosphodiesterases, Type 3 / drug effects
  • Cyclic Nucleotide Phosphodiesterases, Type 3 / genetics
  • Cyclic Nucleotide Phosphodiesterases, Type 3 / metabolism*
  • Enzyme Inhibitors / pharmacology
  • Gene Expression Regulation, Enzymologic*
  • Human Umbilical Vein Endothelial Cells
  • Humans
  • Macrophages / metabolism
  • Milrinone / pharmacology
  • Tetrazoles / pharmacology
  • Transcription, Genetic*
  • Ubiquitination

Substances

  • Antigens, CD
  • Enzyme Inhibitors
  • Tetrazoles
  • 8-Bromo Cyclic Adenosine Monophosphate
  • Cyclic Nucleotide Phosphodiesterases, Type 3
  • Adenosine Triphosphatases
  • Apyrase
  • CD39 antigen
  • Milrinone
  • Cilostazol