Versatile post-functionalization of polyoxometalate platforms by using an unprecedented range of palladium-catalyzed coupling reactions

Abstract

Handy POMs: Several palladium-catalyzed coupling reactions have been applied to polyoxometalate post-functionalization. The feasibility of each reaction with one model substrate was investigated and each set of synthetic conditions was optimized to obtain full conversions and high purity hybrid compounds.

Keywords: cross-coupling; organic-inorganic hybrids; palladium; polyoxometalates.