Enzymes that control the conversion of L-tryptophan-nicotinamide and the urinary excretion ratio (N(1)-methyl-2-pyridone-5-carboxamide + N(1)-methyl-4-pyridone-3-carboxamide)/N(1)-methylnicotinamide in mice

Biosci Biotechnol Biochem. 2013;77(10):2105-11. doi: 10.1271/bbb.130467. Epub 2013 Oct 7.

Abstract

There is little information on L-tryptophan→nicotinamide metabolism in mice. In the present study, we investigated the two important nutritional factors involved in metabolism L-tryptophan→nicotinamide; one is the amount of nicotinamide synthesized from L-tryptophan, and the other is the urine ratio (N(1)-methyl-2-pyridone-5-carboxamide + N(1)-methyl-4-pyridone-3-carboxamide)/N(1)-methylnicotinamide. The order of the percentages of nicotinamide synthesized from L-tryptophan was as follows: CBA strain mice (conversion percentage 0.41%) < BALB strain mice (0.82%) < C57BL/6 strain mice (1.13%) < ICR strain mice (1.70%). Urinary excretion of quinolinic acid was correlated with urinary excretion of the sum of nicotinamide and its catabolites (p<0.0001). The urine sum, which reflects the conversion of L-tryptophan→nicotinamide, correlated well with the activity of 3-hydroxyanthranilic acid dioxygenase (p=0.040). A nutritional indicator, the urine ratio (N(1)-methyl-2-pyridone-5-carboxamide + N(1)-methyl-4-pyridone-3-carboxamide)/N(1)-methylnicotinamide, was controlled by the activity of N(1)-methyl-2-pyridone-5-carboxamide-forming N(1)-methylnicotinamide oxidase.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Body Weight
  • Eating
  • Enzymes / metabolism*
  • Male
  • Mice
  • NAD / metabolism
  • Niacinamide / analogs & derivatives*
  • Niacinamide / metabolism
  • Niacinamide / urine
  • Pyridones / metabolism
  • Pyridones / urine*
  • Quinolinic Acid / metabolism
  • Tryptophan / metabolism*

Substances

  • Enzymes
  • Pyridones
  • l-methyl-2-pyridone-5-carboxamide
  • NAD
  • Niacinamide
  • N(1)-methyl-4-pyridone-5-carboxamide
  • Tryptophan
  • Quinolinic Acid
  • N(1)-methylnicotinamide