The effect of hydrosilanes on the active sites of the Phillips catalyst: the secret for in situ α-olefin generation

Chemistry. 2013 Dec 16;19(51):17277-82. doi: 10.1002/chem.201303156. Epub 2013 Nov 14.

Authors

Caterina Barzan¹, Diego Gianolio, Elena Groppo, Carlo Lamberti, Vincent Monteil, Elsje Alessandra Quadrelli, Silvia Bordiga

Affiliation

¹ Department of Chemistry, NIS and INSTM, University of Turin, Via Quarello 15A, 10135 Turin (Italy).

PMID: 24243525
DOI: 10.1002/chem.201303156

No abstract available

Keywords: Phillips catalyst; chromium; ethylene oligomerization; heterogeneous catalysis; linear-low-density polyethylene.