Polyacrylamide-based biocompatible Nanoplatform enhances the tumor uptake, PET/fluorescence imaging and anticancer activity of a chlorophyll analog

Theranostics. 2014 Mar 16;4(6):614-28. doi: 10.7150/thno.8478. eCollection 2014.

Abstract

In this report we demonstrate the outstanding advantages of multifunctional nanoplatforms for cancer-imaging and therapy. The non-toxic polyacrylamide (PAA) nanoparticles (size:18-25 nm) formulation drastically changed the pharmacokinetic profile of the ¹²⁴I- labeled chlorophyll-a derivative (formulated in 10% ethanol in PBS) with a remarkable enhancement in tumor uptake, and significantly reduced uptake in spleen and liver. Among the various nanoformulations investigated, the ¹²⁴I- labeled photosensitizer (dose: 0.6142 MBq), and the cyanine dye-nanoparticles (CD-NP) conjugate (dose 0.3 μmol/kg) in combination showed great potential for tumor imaging (PET/NIR fluorescence) in BALB/c mice bearing Colon26 tumors. Compared to free non-labeled photosensitizer, the corresponding PAA nanoformulation under similar treatment parameters showed a remarkable enhancement in long-term tumor cure by PDT (photodynamic therapy) and provides an opportunity to develop a single nanoplatform for tumor-imaging (PET/fluorescence) and phototherapy, a practical "See and Treat" approach.

Keywords: Nanoparticles; Positron Imaging Tomography; Reactive Oxygen species.; photodynamic therapy.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Chlorophyll / analogs & derivatives*
  • Chlorophyll / chemistry
  • Chlorophyll / pharmacokinetics
  • Chlorophyll / therapeutic use
  • Colonic Neoplasms / diagnostic imaging*
  • Colonic Neoplasms / drug therapy
  • Iodine Radioisotopes / chemistry
  • Iodine Radioisotopes / pharmacokinetics
  • Mice
  • Mice, Inbred BALB C
  • Nanoparticles / chemistry*
  • Nanoparticles / therapeutic use
  • Photochemotherapy*
  • Photosensitizing Agents / chemistry*
  • Photosensitizing Agents / pharmacokinetics
  • Photosensitizing Agents / therapeutic use
  • Positron-Emission Tomography*
  • Tomography, Optical

Substances

  • Iodine Radioisotopes
  • Photosensitizing Agents
  • methyl 3-(1'-3-iodobenzyloxyethyl)-3-devinylpyropheophorbide-a
  • Chlorophyll