Bleomycin sulphate loaded nanostructured lipid particles augment oral bioavailability, cytotoxicity and apoptosis in cervical cancer cells

Colloids Surf B Biointerfaces. 2014 Jun 1:118:101-10. doi: 10.1016/j.colsurfb.2014.03.036. Epub 2014 Mar 29.

Abstract

In present investigation, bleomycin sulphate loaded nanostructured lipid particles (BLM-NLPs) were constructed to enhance the oral bioavailability by overwhelming the first pass hepatic metabolism. The particles size and nanoencapsulation efficiency of BLM-NLPs were measured to be 17.4±5.4nm and 45.3±3.4%, respectively. Our studies indicated that the drug was molecularly dispersed in the lipid nanocoacervates, with amorphous geometry, without altering the chemical structure, as ascertained by spectral studies. The nanoformulation, BLM-NLPs was analyzed for dissolution testing, cytotoxicity, apoptosis and cellular uptake in human cervical cancer cell line, HeLa cells. BLM-NLPs released the drug with first order kinetic in simulated intestinal fluid (pH∼6.8±0.1), characterized by initial burst and followed by slow release. Further, an enhanced cytotoxicity (∼5.6 fold lower IC50), improved intracellular concentration (∼4.38 fold) and greater degree of apoptosis was induced by BLM-NLPs in HeLa cells, as compared to BLM alone. Moreover, BLM-NLPs also showed dose-dependent internalization, as evinced by cellular uptake study. The in vivo study indicated a significantly (P<0.0001) smaller elimination rate constant (KE), volume of distribution (Vd) and clearance rate (CLTotal) for BLM-NLPs, as compared to BLM solution in post-oral administrations. This clearly depicts the retention and stability of tailored nanoformulation in intestinal absorption pathway. In addition, our nanoformulation, BLM-NLPs documented significantly (P<0.0001)∼3.4 fold (66.20±2.57%) higher bioavailability than BLM solution (19.56±0.79%). In conclusion, our in vitro and in vivo results warrant the safety, efficacy and potency of tailored nanoformulation in clinical settings.

Keywords: Apoptosis; Bioavailability; Bleomycin sulphate; Cellular uptake; Cytotoxicity; Nanostructured lipid particles.

MeSH terms

  • Administration, Oral
  • Animals
  • Apoptosis / drug effects*
  • Biological Availability
  • Bleomycin / blood
  • Bleomycin / pharmacokinetics
  • Bleomycin / pharmacology*
  • Bleomycin / therapeutic use
  • Calorimetry, Differential Scanning
  • Chromatography, High Pressure Liquid
  • Female
  • HeLa Cells
  • Humans
  • Intracellular Space / drug effects
  • Intracellular Space / metabolism
  • Kinetics
  • Lipids / chemistry*
  • Mice
  • Microscopy, Atomic Force
  • Nanostructures / chemistry*
  • Nanostructures / ultrastructure
  • Particle Size
  • Spectroscopy, Fourier Transform Infrared
  • Static Electricity
  • Time Factors
  • Uterine Cervical Neoplasms / drug therapy
  • Uterine Cervical Neoplasms / pathology*
  • X-Ray Diffraction

Substances

  • Lipids
  • Bleomycin