1D spectral imaging was used to characterize the K-shell emission of Z ≈ 30-35 and Z ≈ 40-42 laser-irradiated foils at the National Ignition Facility. Foils were driven with up to 60 kJ of 3ω light, reaching laser irradiances on target between 0.5 and 20 × 10(15) W/cm(2). Laser-to-X-ray conversion efficiency (CE) into the Heα line (plus satellite emission) of 1.0%-1.5% and 0.15%-0.2% was measured for Z ≈ 30-32 and Z ≈ 40-42, respectively. Measured CE into Heα (plus satellite emission) of Br (Z = 35) compound foils (either KBr or RbBr) ranged between 0.16% and 0.29%. Measured spectra are compared with 1D non-local thermodynamic equilibrium atomic kinetic and radiation transport simulations, providing a fast and accurate predictive capability.