Simultaneous determination of stable carbon, oxygen, and hydrogen isotopes in cellulose

Anal Chem. 2015 Jan 6;87(1):376-80. doi: 10.1021/ac502557x. Epub 2014 Dec 11.

Abstract

A technological development is described through which the stable carbon-, oxygen-, and nonexchangeable hydrogen-isotopic ratios (δ(13)C, δ(18)O, δ(2)H) are determined on a single carbohydrate (cellulose) sample with precision equivalent to conventional techniques (δ(13)C 0.15‰, δ(18)O 0.30‰, δ(2)H 3.0‰). This triple-isotope approach offers significant new research opportunities, most notably in physiology and medicine, isotope biogeochemistry, forensic science, and palaeoclimatology, when isotopic analysis of a common sample is desirable or when sample material is limited.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon Isotopes / analysis*
  • Cellulose / chemistry*
  • Hydrogen / analysis*
  • Mass Spectrometry / methods*
  • Oxygen Isotopes / analysis*

Substances

  • Carbon Isotopes
  • Oxygen Isotopes
  • Hydrogen
  • Cellulose