Preclinical to clinical translation of CNS transporter occupancy of TD-9855, a novel norepinephrine and serotonin reuptake inhibitor

Int J Neuropsychopharmacol. 2014 Dec 13;18(2):pyu027. doi: 10.1093/ijnp/pyu027.

Abstract

Background: Monoamine reuptake inhibitors exhibit unique clinical profiles that reflect distinct engagement of the central nervous system (CNS) transporters.

Methods: We used a translational strategy, including rodent pharmacokinetic/pharmacodynamic modeling and positron emission tomography (PET) imaging in humans, to establish the transporter profile of TD-9855, a novel norepinephrine and serotonin reuptake inhibitor.

Results: TD-9855 was a potent inhibitor of norepinephrine (NE) and serotonin 5-HT uptake in vitro with an inhibitory selectivity of 4- to 10-fold for NE at human and rat transporters. TD-9855 engaged norepinephrine transporters (NET) and serotonin transporters (SERT) in rat spinal cord, with a plasma EC50 of 11.7 ng/mL and 50.8 ng/mL, respectively, consistent with modest selectivity for NET in vivo. Accounting for species differences in protein binding, the projected human NET and SERT plasma EC50 values were 5.5 ng/mL and 23.9 ng/mL, respectively. A single-dose, open-label PET study (4-20mg TD-9855, oral) was conducted in eight healthy males using the radiotracers [(11)C]-3-amino-4- [2-[(di(methyl)amino)methyl]phenyl]sulfanylbenzonitrile for SERT and [(11)C]-(S,S)-methylreboxetine for NET. The long pharmacokinetic half-life (30-40 h) of TD-9855 allowed for sequential assessment of SERT and NET occupancy in the same subject. The plasma EC50 for NET was estimated to be 1.21 ng/mL, and at doses of greater than 4 mg the projected steady-state NET occupancy is high (>75%). After a single oral dose of 20mg, SERT occupancy was 25 (±8)% at a plasma level of 6.35 ng/mL.

Conclusions: These data establish the CNS penetration and transporter profile of TD-9855 and inform the selection of potential doses for future clinical evaluation.

Keywords: PET; TD-9855; norepinephrine and serotonin transporter; pain.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adult
  • Aniline Compounds
  • Animals
  • Blood Chemical Analysis
  • Brain / diagnostic imaging
  • Brain / drug effects
  • Brain / metabolism
  • Half-Life
  • Humans
  • Magnetic Resonance Imaging
  • Male
  • Models, Biological
  • Morpholines
  • Neurotransmitter Uptake Inhibitors / pharmacokinetics*
  • Neurotransmitter Uptake Inhibitors / pharmacology*
  • Norepinephrine Plasma Membrane Transport Proteins / metabolism
  • Phenyl Ethers / pharmacokinetics*
  • Phenyl Ethers / pharmacology*
  • Piperidines / pharmacokinetics*
  • Piperidines / pharmacology*
  • Positron-Emission Tomography
  • Radiopharmaceuticals
  • Rats, Sprague-Dawley
  • Reboxetine
  • Serotonin Plasma Membrane Transport Proteins / metabolism
  • Spinal Cord / drug effects
  • Spinal Cord / metabolism
  • Sulfides

Substances

  • 3-amino-4-(2-dimethylaminomethylphenylsulfanyl)benzonitrile
  • Aniline Compounds
  • Morpholines
  • Neurotransmitter Uptake Inhibitors
  • Norepinephrine Plasma Membrane Transport Proteins
  • O-methyl reboxetine
  • Phenyl Ethers
  • Piperidines
  • Radiopharmaceuticals
  • SLC6A2 protein, human
  • SLC6A4 protein, human
  • Serotonin Plasma Membrane Transport Proteins
  • Slc6a2 protein, rat
  • Slc6a4 protein, rat
  • Sulfides
  • ampreloxetine
  • Reboxetine