Dextrin-based nanomagnetogel: in vivo biodistribution and stability

Bioconjug Chem. 2015 Apr 15;26(4):699-706. doi: 10.1021/acs.bioconjchem.5b00024. Epub 2015 Mar 12.

Abstract

The biodistribution profile of a new dextrin nanomagnetogel, which consists of γ-Fe2O3 superparamagnetic nanoparticles loaded within a polymeric matrix of modified dextrin, was studied in mice. The nanomagnetogel bear a monomodal size distribution profile (average diameter 110 nm) close to neutral surface charge and higher relaxivity (r2 = 215-248 mM(-1) s(-1) and r2/r1 = 13-11) than those of commercial formulations (r2 = 160-177 mM(-1) s(-1) and r2/r1 = 4-7). Also, the observed blood half-life-approximately 4 h-is superior to that of similar commercially available formulations, which remain for a few minutes in circulation. PEGylation resulted in 1.7- and 1.2-fold lower accumulation in the liver and spleen, respectively, within the first 24 h. Noteworthy, a good correlation was obtained between the amount of polymer (quantified by scintigraphy) in the spleen, 48 h after administration, and the amount of iron physically loaded through hydrophobic interactions (quantified by ICP) indicating the absence of iron leakage from the polymeric matrix. This study provides evidence of the in vivo stability of a self-assembled nanomagnetogel, a relevant feature which is seldom reported in the literature.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Dextrins / chemistry
  • Dextrins / pharmacokinetics*
  • Drug Carriers*
  • Drug Stability
  • Ferric Compounds / chemistry
  • Ferric Compounds / pharmacokinetics*
  • Gels
  • Half-Life
  • Hydrophobic and Hydrophilic Interactions
  • Liver / drug effects
  • Liver / metabolism
  • Liver / ultrastructure
  • Magnetic Resonance Imaging
  • Magnetite Nanoparticles / chemistry*
  • Magnetite Nanoparticles / ultrastructure
  • Mice
  • Polyethylene Glycols / chemistry
  • Spleen / drug effects
  • Spleen / metabolism
  • Spleen / ultrastructure
  • Static Electricity
  • Surface Properties
  • Tomography, Emission-Computed, Single-Photon

Substances

  • Dextrins
  • Drug Carriers
  • Ferric Compounds
  • Gels
  • Magnetite Nanoparticles
  • ferric oxide
  • Polyethylene Glycols