Simultaneous enhancement of upconversion and downshifting luminescence via plasmonic structure

Nano Lett. 2015 Apr 8;15(4):2491-7. doi: 10.1021/nl5049803. Epub 2015 Mar 13.

Abstract

We describe a metal nanodisk-insulator-metal (MIM) structure that enhances lanthanide-based upconversion (UC) and downshifting (DS) simultaneously. The structure was fabricated using a nanotransfer printing method that facilitates large-area applications of nanostructures for optoelectronic devices. The proposed MIM structure is a promising way to harness the entire solar spectrum by converting both ultraviolet and near-infrared to visible light concurrently through resonant-mode excitation. The overall photoluminescence enhancements of the UC and DS were 174- and 29-fold, respectively.

Keywords: Upconversion; downshifting; energy transfer; metal nanopattern; nanotransfer printing; plasmonic structure; solar spectrum conversion.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Light
  • Luminescent Measurements / methods*
  • Materials Testing
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / ultrastructure*
  • Molecular Imprinting / methods*
  • Scattering, Radiation
  • Silver / chemistry*
  • Surface Plasmon Resonance / methods*

Substances

  • Silver