Synthesis and photochemical reactions of nitroestrogens: possible photoaffinity labels of zero length

Steroids. 1989 Oct;54(4):441-52. doi: 10.1016/0039-128x(89)90055-x.

Abstract

The syntheses of 3,4-dimethoxy-1,3,5(10)-estratrien-17-one and 4-bromo-3-methoxy-2-nitro-1,3,5(10)-estratrein-17-one are described and their photoreactions with amines and hydroxide ion studied. The possible usefulness of these new steroids as photoaffinity labels of zero length is discussed.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Affinity Labels*
  • Chemical Phenomena
  • Chemistry
  • Estrone / analogs & derivatives*
  • Nitro Compounds / chemical synthesis*
  • Photometry / methods*

Substances

  • Affinity Labels
  • Nitro Compounds
  • 3,4-dimethoxy-1-nitro-1,3,5(10)-estratrien-17-one
  • 4-bromo-3-methoxy-2-nitro-1,3,5(10)-estratriene-17-one
  • Estrone