N-acetylcysteine interference of Trinder-based assays

Clin Biochem. 2016 Jan;49(1-2):100-4. doi: 10.1016/j.clinbiochem.2015.10.005. Epub 2015 Oct 21.

Abstract

Objectives: The primary objective of this study was to evaluate potential interference of Trinder-based chemistry assays by N-acetylcysteine (NAC). A secondary objective was to look for evidence of interference in patients treated with NAC for acetaminophen (APAP) overdose.

Design and methods: Dilutions of NAC in plasma were tested for interference using the following Roche Diagnostics Trinder-based assays on a cobas 8000 system: enzymatic creatinine (Cr), cholesterol (CHOL), high-density lipoprotein cholesterol (HDL-C), triglycerides (TRIG), and uric acid (UA). Two non-Trinder Roche assays - urea nitrogen (BUN) and glucose (GLUC) - were tested as controls. Sekisui N-geneous® low-density lipoprotein cholesterol (LDL-C) reagent was also evaluated. Retrospective chart review of APAP overdose cases over 49months was conducted to look for differences in plasma Cr before and after intravenous (IV) NAC administration.

Results: NAC concentrations (shown in parentheses) that caused ≥10% inhibition for individual assays were (in order of sensitivity to interference): TRIG (570mg/L)>CHOL (740mg/L)≈Cr (790mg/L)>UA (1100mg/L)>HDL-C (1760mg/L)>LDL-C (2900mg/L). Neither BUN nor GLUC achieved significant inhibition up to 10,000mg/L NAC. Evidence for relatively minor inhibition of Cr was observed in patients after NAC administration.

Conclusions: NAC inhibition of the assays investigated typically occurs at concentrations higher than expected during IV and oral NAC therapy.

Keywords: Acetaminophen; Interference; N-acetylcysteine; Overdose; Paracetamol; Toxicity; Trinder reaction.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acetaminophen / poisoning*
  • Acetylcysteine / blood
  • Acetylcysteine / therapeutic use*
  • Ferric Compounds / chemistry*
  • Humans
  • Poisoning / drug therapy
  • Retrospective Studies

Substances

  • Ferric Compounds
  • Acetaminophen
  • Trinder's reagent
  • Acetylcysteine