Two new lignans from the aerial part of Vitex negundo

J Asian Nat Prod Res. 2016 Jul;18(7):656-61. doi: 10.1080/10286020.2016.1142975. Epub 2016 Mar 21.

Abstract

A new phenyldihydronaphthalene-type lignan, (3R,4S)-6-hydroxy-4-(4-hydroxy- 3-methoxyphenyl)-5,7-dimethoxy-3,4-dihydro-2-naphthaldehyde-3a-O-β-d-glucopyranoside (1), and a new phenylnaphthalene-type lignan, 6,7,4'-trihydroxy-3'-methoxy-2,3- cycloligna-1,4-dien-2a,3a-olide (2), along with 10-known lignan derivatives (3-12) were isolated from the aerial part of Vitex negundo var. heterophylla. Their structures were established by comprehensive 1D- and 2D-NMR spectroscopic analyses.

Keywords: Verbenaceae; Vitex negundo var. heterophylla; lignan; vitecannaside; vitexdoin.

MeSH terms

  • Drugs, Chinese Herbal / chemistry
  • Drugs, Chinese Herbal / isolation & purification*
  • Glucosides / chemistry
  • Glucosides / isolation & purification*
  • Lignans / chemistry
  • Lignans / isolation & purification*
  • Molecular Structure
  • Nuclear Magnetic Resonance, Biomolecular
  • Plant Components, Aerial / chemistry*
  • Vitex / chemistry*

Substances

  • (3R,4S)-6-hydroxy-4-(4-hydroxy- 3-methoxyphenyl)-5,7-dimethoxy-3,4-dihydro-2-naphthaldehyde-3alpha-O-beta-D-glucopyranoside
  • Drugs, Chinese Herbal
  • Glucosides
  • Lignans