Small-pore driven high capacitance in a hierarchical carbon via carbonization of Ni-MOF-74 at low temperatures

J A Carrasco; J Romero; G Abellán; J Hernández-Saz; S I Molina; C Martí-Gastaldo; E Coronado

doi:10.1039/c6cc02252a

Small-pore driven high capacitance in a hierarchical carbon via carbonization of Ni-MOF-74 at low temperatures

Chem Commun (Camb). 2016 Jul 12;52(58):9141-4. doi: 10.1039/c6cc02252a.

Authors

J A Carrasco¹, J Romero¹, G Abellán², J Hernández-Saz³, S I Molina³, C Martí-Gastaldo¹, E Coronado¹

Affiliations

¹ Instituto de Ciencia Molecular, Universitat de València, Catedrático José Beltrán 2, 46980, Paterna, Spain. carlos.marti@uv.es.
² Department of Chemistry and Pharmacy and Joint Institute of Advanced Materials and Processes (ZMP), University Erlangen-Nürnberg, Henkestr. 42, 91054 Erlangen and Dr.-Mack Str. 81, 90762 Fürth, Germany.
³ Departamento de Ciencia de los Materiales e I.M. y Q.I., Facultad de Ciencias, IMEYMAT, Universidad de Cádiz, Campus Río San Pedro, s/n, 11510, Cádiz, Spain.

PMID: 27128345
DOI: 10.1039/c6cc02252a

Abstract

A hierarchical porous carbon prepared via direct carbonization of Ni-MOF-74 loaded with furfuryl alcohol at 450 °C displays high specific capacitance in comparison with other MOF-derived carbons as a result of the formation of micropores smaller than 1 nm.