Preparation and Characterization of Gelonin-Melittin Fusion Biotoxin for Synergistically Enhanced Anti-Tumor Activity

Pharm Res. 2016 Sep;33(9):2218-2228. doi: 10.1007/s11095-016-1959-4. Epub 2016 Jun 1.

Abstract

Purpose: To investigate the applicability of fusion biotoxins combining pore-forming toxins (PFTs) and ribosome-inactivating proteins (RIPs) for the anti-cancer treatment.

Methods: Membrane active PFTs tend to destabilize cell membranes of tumor cells, but lack a warhead inducing significant cause of cell death. Cell-impermeable RIPs possess a powerful warhead, yet not able to enter the tumor cells. To address these challenges for anti-tumor effects, we introduced a fusion strategy of conjugating melittin (a PFT) and gelonin (a type 1 RIP) via chemical and recombinant methods, followed by in vitro assays and in vivo animal studies.

Results: In vitro characterization results confirmed that the chimeric gelonin-melittin fusion proteins retained equivalent intrinsic activity to that of unmodified gelonin in inhibiting protein translation. However, chemically conjugated gelonin-melittin (cGel-Mel) and recombinant chimeric gelonin-melittin fusion (rGel-Mel) exhibited greater cell uptake, yielding a significantly enhanced cytotoxic activity over treatment of gelonin, melittin or physical mixture of gelonin and melittin. Remarkably, cGel-Mel and rGel-Mel displayed 32- and 10-fold lower IC50 than gelonin in the cell lines. The superior anti-tumor efficacy of multivalent cGel-Mel to monovalent rGel-Mel suggested that valency could be a crucial factor for the extent of melittin-mediated cell uptake. Tumoricidal effects observed from animal studies were in good accordance with our findings from the cellular assays.

Conclusions: This study successfully demonstrated that fusion of biotoxins could provide a simple yet effective way to synergistically augment their anti-tumor activity.

Keywords: cancer; gelonin; melittin; ribosome inactivating protein; toxin.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, N.I.H., Extramural

MeSH terms

  • Animals
  • Antineoplastic Agents, Phytogenic / chemistry*
  • Antineoplastic Agents, Phytogenic / pharmacology
  • Cell Line
  • Cell Line, Tumor
  • Dogs
  • HeLa Cells
  • Humans
  • Madin Darby Canine Kidney Cells
  • Melitten / chemistry*
  • Melitten / pharmacology
  • Mice
  • Neoplasms / drug therapy
  • Rats
  • Recombinant Fusion Proteins / chemistry*
  • Recombinant Fusion Proteins / pharmacology
  • Ribosome Inactivating Proteins / chemistry
  • Ribosome Inactivating Proteins / pharmacology
  • Ribosome Inactivating Proteins, Type 1 / chemistry*
  • Ribosome Inactivating Proteins, Type 1 / pharmacology
  • Toxins, Biological / chemistry*
  • Toxins, Biological / pharmacology

Substances

  • Antineoplastic Agents, Phytogenic
  • Recombinant Fusion Proteins
  • Ribosome Inactivating Proteins, Type 1
  • Toxins, Biological
  • Melitten
  • GEL protein, Gelonium multiflorum
  • Ribosome Inactivating Proteins