Assessment of Metformin-Induced Changes in Cardiac and Hepatic Redox State Using Hyperpolarized[1-13C]Pyruvate

Diabetes. 2016 Dec;65(12):3544-3551. doi: 10.2337/db16-0804. Epub 2016 Aug 25.

Abstract

Metformin improves cardiovascular outcomes in type 2 diabetes, but its exact mechanisms of action remain controversial. We used hyperpolarized [1-13C]pyruvate magnetic resonance spectroscopy to determine the effects of metformin treatment on heart and liver pyruvate metabolism in rats in vivo. Both oral treatment for 4 weeks and a single intravenous metformin infusion significantly increased the cardiac [1-13C]lactate:[1-13C]pyruvate ratio but had no effect on the [1-13C]bicarbonate + 13CO2:[1-13C]pyruvate ratio, an index of pyruvate dehydrogenase flux. These changes were paralleled by a significant increase in the heart and liver cytosolic redox state, estimated from the [lactate]:[pyruvate] ratio but not the whole-cell [NAD+]/[NADH] ratio. Hyperpolarized MRI localized the increase in cardiac lactate to the left ventricular myocardium, implying a direct myocardial effect, though metformin had no effect on systolic or diastolic cardiac function. These findings demonstrate the ability of hyperpolarized pyruvate magnetic resonance spectroscopy to detect metformin-induced changes in cytosolic redox biology, suggest that metformin has a previously unrecognized effect on cardiac redox state, and help to refine the design of impending hyperpolarized magnetic resonance studies in humans.

MeSH terms

  • Animals
  • Bicarbonates / metabolism
  • Carbon Isotopes / chemistry*
  • Carbon Isotopes / metabolism
  • Heart / drug effects*
  • Lactic Acid / metabolism
  • Liver / drug effects*
  • Liver / metabolism*
  • Magnetic Resonance Imaging
  • Magnetic Resonance Spectroscopy
  • Male
  • Metformin / pharmacology*
  • Myocardium / metabolism*
  • Oxidation-Reduction
  • Pyruvic Acid / chemistry*
  • Pyruvic Acid / metabolism
  • Rats
  • Rats, Wistar

Substances

  • Bicarbonates
  • Carbon Isotopes
  • Lactic Acid
  • Pyruvic Acid
  • Metformin